Bis(dibenzylideneacetone)palladium, Pd : 18.4 wt.%

Typical Properties
CAS	32005-36-0
Catalog	ACM32005360-2
Molecular Weight	575 g/mol
Canonical SMILES	[Pd].O=C(/C=C/c1ccccc1)\C=C\c2ccccc2.O=C(/C=C/c3ccccc3)\C=C\c4ccccc4
InChI	1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;
InChI Key	UKSZBOKPHAQOMP-SVLSSHOZSA-N
Melting Point	150 °C
Appearance	Powder
Storage	2-8 °C
Color	Red-brown to black
Composition	(C6H5CH=CHCOCH=CHC6H5)2Pd
EC Number	608-691-6
MDL Number	MFCD00051942
Quality Level	100
Shipping	Ambient

Overview

Description

Bis(dibenzylideneacetone)palladium (Pd(dba)2) is an air-stable Pd0 complex. It is a reagent for the synthesis of allyl-substituted cyclopentadiene. It is a homogeneous catalyst that can catalyze the alkylation of allyl acetate by the action of various nucleophiles under mild conditions.

Features

·High catalytic activity
·Good selectivity
·Use safety
·High temperature resistance, oxidation resistance, corrosion resistance
·Recyclable recycling processing

Application

·Synthesis of isomer 2-aryl-2,5-dihydrofuran by Heck coupling reaction of aryl bromide with alkene using neopentylphosphine ligand;
·Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand;
·Allylation of stable anions;
·Cross-coupling of allyl, alkenyl and aryl halides with organotin compounds;
·Cross-coupling of vinyl halides with alkenyl zinc compounds;
·Carbonylation of alkenyl and aryl halides;
·Efficient oxidation of alcohols to aldehydes and ketones together with cyclic thiourea ligands;